Thanks for the replies. It's all stuff worth noting for future reference but because of the amount of work involved in constructing a rotary tippler, it is going to be a last resort.
The hopper door release worked quite well but what I didn't account for was the load not wanting to drop out of the hopper. Because the loads are supposed to be shovelled in straight off the quarry floor after blasting I wanted some reasonably large lumps but these simply locked together when the door fell open, because the aperture in the hopper bottom isn't large enough, and needed manual intervention. The size of the aperture is of course limited by the back-to-backs of the wheelsets and the length of the hopper bottom, so the only thing I could do was to have fewer large lumps in the mix. It got to the point that for the load to drop reliably I had far more small rocks than seemed realistic, so the hopper idea has gone.
I'm now on with American-style dump cars. The Oxfordshire Ironstone Company and Lloyds Ironstone Company used this type of wagon on standard gauge in the UK, as did Mountsorrel granite quarries, so I see no reason why Harboro Stone Co. couldn't use them for limestone.
The door lifts as the body tips and so there is a far larger gap for the large rocks to pass through on the model, so I'm hoping these work.
I started off with some second hand Bachmann On30 wagons. Although they are O scale narrow gauge, the bar frames look the part and are no wider over the axleboxes than an ordinary British wagon. The length and wheelbase are about right too. The bodies, on the other hand, are huge!
That problem was soon solved. I had to also make new support/pivots in order to bring the body down to nearer the correct height for 4mm. The Lloyds prototypes were 7ft. 6in. tall and mine now scales at about 8ft.

I still have to put in the intermediate pivot/supports and also need to make the balancing arms for the door opening mechanism. Once those basics are done, and the wagon tested to ensure it can actually dump its load, I will add exterior detail such as reinforcing angle iron and rivets.